Observations in Daily Life:
- Milk spoils when left at room temperature in summers.
- Iron objects rust when exposed to humid air.
- Grapes undergo fermentation.
- Cooking food changes its nature.
- Digestion alters food composition.
- Respiration produces energy by breaking down food.
- In all these examples, the original substance changes its nature and identity, indicating chemical changes.
- A chemical reaction happens when a chemical change occurs.
Indicators of a Chemical Reaction:
- Change in state (solid, liquid, gas).
- Change in color (e.g., rust forming on iron).
- Evolution of gas (e.g., bubbles in a reaction).
- Change in temperature (e.g., heat produced or absorbed).
Word Equations:
- Word Equation Example:
- Burning magnesium:
Magnesium + Oxygen → Magnesium oxide
- Burning magnesium:
- Key Terms:
- Reactants: Substances that react (e.g., magnesium and oxygen).
- Products: Substances formed (e.g., magnesium oxide).
- The arrow (→) indicates the direction of the reaction.
Chemical Equations:
- Replacing words with chemical symbols makes reactions concise:
- Example: Mg + O₂ → MgO
- Balanced vs. Unbalanced Equations:
- A balanced equation has the same number of atoms of each element on both sides.
- An unbalanced equation violates the law of conservation of mass, which states:
- “Mass cannot be created or destroyed in a chemical reaction.”
Steps to Balance a Chemical Equation:
- Identify reactants and products: Write their chemical formulas.
- Draw boxes around formulas to avoid altering them.
- Count atoms of each element on both sides.
- Balance one element at a time:
- Use coefficients (numbers before formulas) to equalize atoms.
- Check the balance for all elements.
- Add physical states (if needed):
- (s): solid, (l): liquid, (g): gas, (aq): aqueous (dissolved in water).
Examples:
- Magnesium Burning:
- Skeletal equation: Mg + O₂ → MgO
- Balanced equation: 2Mg + O₂ → 2MgO
- Reaction of Zinc with Sulfuric Acid:
- Zn + H₂SO₄ → ZnSO₄ + H₂ (already balanced).
- Balancing Iron and Water Reaction:
- Skeletal equation: Fe + H₂O → Fe₃O₄ + H₂
- Step-by-step balancing:
- Balance oxygen: 4H₂O → Fe₃O₄
- Balance hydrogen: 4H₂
- Balance iron: 3Fe
- Final equation: 3Fe + 4H₂O → Fe₃O₄ + 4H₂
Enhancing Equations:
- Add reaction conditions (e.g., temperature, pressure, catalyst):
- Example: CO(g) + 2H₂(g) → CH₃OH(l) (at 340 atm).
- Include physical states for better clarity:
- Example: 3Fe(s) + 4H₂O(g) → Fe₃O₄(s) + 4H₂(g).
Basics of Chemical Reactions
- Atoms don’t change into other elements, nor do they disappear or reappear; reactions involve breaking and forming bonds.
- Chemical reactions produce new substances through rearranging atoms.
1. Combination Reaction
- Definition: Two or more reactants combine to form one product.
- Example: CaO + H2O → Ca(OH)2 (Calcium oxide reacts with water to form calcium hydroxide).
- Exothermic Reaction: Heat is released during combination reactions.
- Examples:
- Burning coal: C + O2 → CO2
- Formation of water: 2H2 + O2 → 2H2O
- Examples:
- Real-life relevance:
- Whitewashing: Slaked lime reacts with CO2 in air to form shiny calcium carbonate (CaCO3).
2. Decomposition Reaction
- Definition: A single compound breaks into two or more simpler substances.
- Example: CaCO3 → CaO+CO2 (Limestone decomposes to quicklime and carbon dioxide).
- Types:
- Thermal Decomposition: Heat is used to break the compound.
- Example: 2FeSO4 → Fe2O3+SO2+SO3
- Photolytic Decomposition: Light causes the breakdown.
- Example: 2AgCl → 2Ag+Cl2 (Used in black-and-white photography).
- Electrolytic Decomposition: Electricity breaks the compound.
- Example: Electrolysis of water produces hydrogen and oxygen gases.
- Thermal Decomposition: Heat is used to break the compound.
- Endothermic Reaction: Energy is absorbed for decomposition to occur.
3. Displacement Reaction
- Definition: A more reactive element displaces a less reactive one from its compound.
- Example: Fe+CuSO4 → FeSO4+Cu
- Other Examples:
- Zn+CuSO4 → ZnSO4+Cu
- Pb+CuCl2 → PbCl2+Cu
- Competitive insight: The reactivity series of metals determines which element can displace another.
4. Double Displacement Reaction
- Definition: Exchange of ions between two reactants to form new products.
- Example: Na2SO4+BaCl2 → BaSO4+2NaCl
- Precipitation Reaction: A solid (precipitate) is formed during the reaction.
- Example: Formation of barium sulfate (BaSO4).
5. Oxidation and Reduction (Redox Reactions)
- Oxidation: Gain of oxygen or loss of hydrogen.
- Example: 2Cu+O2 → 2CuO (Copper oxidized to copper oxide).
- Reduction: Loss of oxygen or gain of hydrogen.
- Example: CuO+H2 → Cu+H2O (Copper oxide reduced to copper).
- Simultaneous process: Oxidation and reduction happen together in redox reactions.
- Example: ZnO+C → Zn+CO
6. Effects of Oxidation in Everyday Life
- Corrosion:
- Metals like iron rust (reddish-brown coating), copper tarnishes (green), and silver blackens.
- Caused by reactions with moisture, oxygen, and other environmental factors.
- Preventive measures: Paint, galvanization, or alloying.
- Rancidity:
- Fats and oils oxidize over time, changing taste and smell.
- Prevention:
- Use antioxidants in food.
- Store food in airtight containers or flush with inert gases like nitrogen.
Key Concepts and Practice for Competitive Exams
- Combination vs. Decomposition: Opposite processes; one forms a single product, the other breaks into simpler substances.
- Exothermic vs. Endothermic: Know examples and energy flow direction.
- Redox Identification: Practice identifying which substances are oxidized and reduced in a reaction.
- Practical Applications: Relate reactions to daily life processes (e.g., respiration, whitewashing).
Sample Questions
- Why is heat released during slaked lime formation?
- Write balanced equations for the decomposition of lead nitrate and the burning of methane.
- Identify oxidized and reduced substances in CuO+H2 → Cu+H2O.
These notes simplify the text while covering essential concepts for better understanding and competitive exam preparation.
These all are the notes of chapter 1 in science. After some time you get important questions HERE. *#THANKS FOR VISITING, VISIT AGAIN#*😊